INFLUENCE OF THE SOLVENT AND THE RATIO OF STARTING REAGENTS ON THE PROPERTIES OF ORGANIC-INORGANIC PEROVSKITE MAPbI3

P. Torchyniuk, O. V’yunov, V. Vlasyuk, V. Kostylyov, A. Belous
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Abstract

The peculiarities of formation and properties of organiс-inorganic MAPbI3 perovskite films, obtained from solutions with different ratios of starting reagents (PbI2:MAI = 1:1,1:2, and 1:3), in the DMF and DMSO solvents, studied. As the PbI2:MAI ratio increases, the temperature of the formation of a single-phase MAPbI3 perovskite film also increases. The slight changes in the structural and electrophysical characteristics for perovskite films obtained at the  different ratios of PbI2:MAI in DMF and DMSO were found. These changes are related to the solvent that is included in the crystalline structure of perovskite. In the same ratios of starting reagents, DMF is included in the structure of perovskite in a greater amount than DMSO.
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溶剂及起始剂配比对有机-无机钙钛矿MAPbI3性能的影响
研究了在DMF和DMSO溶剂中不同起始试剂配比(PbI2:MAI = 1:1,1:2和1:3)溶液中制备的有机无机MAPbI3钙钛矿膜的形成特性和性能。随着PbI2:MAI比例的增加,单相MAPbI3钙钛矿膜的形成温度也随之升高。在DMF和DMSO中加入不同比例的PbI2:MAI时,钙钛矿薄膜的结构和电物理特性发生了细微的变化。这些变化与钙钛矿晶体结构中所含的溶剂有关。在相同起始试剂的比例下,DMF比DMSO在钙钛矿结构中包含的量更大。
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