Photodegradation of surfactants catalyzed by a TiO2 semiconductor

Hisao Hidaka, Jincai Zhao
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引用次数: 53

Abstract

The photo-oxidation of surfactants catalyzed by a TiO2 semiconductor, which is one of the methods suggested to solve the problem of water pollution, is reviewed on the basis of our earlier reported experimental results. The photodegradation rates of different kinds of surfactants and of various moieties (aromatic, oxyethylene and alkyl groups) in the surfactant structure are discussed. A possible photo-oxidation mechanism at the TiO2/water interface is proposed.

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二氧化钛半导体催化表面活性剂的光降解
本文在前人报道的实验结果的基础上,对二氧化钛半导体催化表面活性剂的光氧化作为解决水污染问题的方法之一进行了综述。讨论了不同类型表面活性剂的光降解速率以及表面活性剂结构中不同基团(芳香族、氧基和烷基)的光降解速率。提出了一种可能的TiO2/水界面光氧化机理。
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