The influence of sodium hydroxide on the rheological properties of pastes and gels of potato, corn and wheat starches

J. Galkin, A. Galkina, J. Liesienė, E. Mazoniene
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Abstract

The subject of the study was corn, wheat and potato starch before and after treatment with sodium hydroxide solution, with the aim to evaluate whether this solution is able to remove lipids and have any effect on the rheological properties of starch pastes and gels. Applying the DSC method, it was noted that after the treatment with the sodium hydroxide solution, the enthalpy difference of the amylose – lipids complex formation/ disruption was lower for wheat and corn starch (32.7 % and 71.9 %, respectively). In case of potato starch, complexes were detected neither before nor after the treatment. The study of the rheological properties showed that after the treatment of wheat and corn starch, their gels became softer, the storage modulus (G ′ ) decreased and the delta angle (δ) increased . At the same time, the potato starch gel had a relatively low G ′ modulus and a high delta angle even without treatment, and the treatment itself had a minor effect on its properties. DOI: http://dx.doi.org/10.5755/j01.ct.62.4.3229
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氢氧化钠对马铃薯、玉米和小麦淀粉糊状和凝胶流变学特性的影响
本研究以氢氧化钠溶液处理前后的玉米、小麦和马铃薯淀粉为研究对象,目的是评价氢氧化钠溶液对淀粉糊和淀粉凝胶的脱脂能力和流变性能的影响。DSC法发现,小麦和玉米淀粉经氢氧化钠溶液处理后,直链淀粉-脂质复合物形成/破坏的焓差较低(分别为32.7%和71.9%)。马铃薯淀粉在处理前和处理后均未检测到配合物。流变学特性研究表明,小麦和玉米淀粉处理后,其凝胶变软,储存模量(G′)减小,δ角(δ)增大。同时,未经处理的马铃薯淀粉凝胶具有较低的G′模量和较高的δ角,处理本身对其性能影响较小。DOI: http://dx.doi.org/10.5755/j01.ct.62.4.3229
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