Dominique Zveguintzoff, Claudette Bois, Nguyen Quy Dao
{"title":"Crystal structure of a new insertion compound formed by PdCl2 and tri-methylamine [(CH3)3NH]2PdCl4.(CH3)3NHCl","authors":"Dominique Zveguintzoff, Claudette Bois, Nguyen Quy Dao","doi":"10.1016/0022-1902(81)80086-3","DOIUrl":null,"url":null,"abstract":"<div><p>The complex 3[(CH<sub>3</sub>)<sub>3</sub>NHCl].pdCl<sub>2</sub> crystallises in the orthorhombic system, space group <em>Pnma</em>: <em>a</em> = 990(1) pm; <em>b</em> = 1209(1) pm; <em>c</em> = 1721(2) pm; <em>Z</em> = 4; <em>d</em><sub>th</sub> = 1.49; <em>d</em><sub>exp</sub> = 1.45. The structure is composed of square planar PdCl<sub>4</sub><sup>2−</sup> ions (average length PdCl = 230 pm), of two ammonium groups, each one equidistant of two chlorine atoms and in <em>cis</em> position to the plane of PdCl<sub>4</sub><sup>2−</sup>. A third (CH<sub>3</sub>)<sub>3</sub>NHCl molecule is in insertion in the structure. This is a new type of solvate in which the insertion molecule is an ion pair.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 12","pages":"Pages 3183-3185"},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80086-3","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Inorganic and Nuclear Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0022190281800863","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
Abstract
The complex 3[(CH3)3NHCl].pdCl2 crystallises in the orthorhombic system, space group Pnma: a = 990(1) pm; b = 1209(1) pm; c = 1721(2) pm; Z = 4; dth = 1.49; dexp = 1.45. The structure is composed of square planar PdCl42− ions (average length PdCl = 230 pm), of two ammonium groups, each one equidistant of two chlorine atoms and in cis position to the plane of PdCl42−. A third (CH3)3NHCl molecule is in insertion in the structure. This is a new type of solvate in which the insertion molecule is an ion pair.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
