{"title":"Crystal Structure of Bis(N-ethyl-N-phenyldithiocarbamato-κ2S,S′)-(2-ethyl-2-oxazoline-κ1N)zinc(II)","authors":"Robert A. Gossage, H. Jenkins","doi":"10.2116/ANALSCIX.24.X155","DOIUrl":null,"url":null,"abstract":"The title material was synthesised by the treatment of [Zn{S2CN(Et)(Ph)}2]2 with excess 2-ethyl-2-oxazoline. The crystal system is triclinic (space group P1 and Z = 2). The unit-cell dimensions are a = 10.2310(4)A, b = 11.4701(5)A, c = 12.1981(5)A with α = 85.952(1)°, β = 75.174(1)°, γ = 72.442(1)° and V = 1319.30(9)A3. The final R value is 0.0248 (4641 observed reflections: I > 2σ(I)). The Zn atom coordinates with two chelating dithiocarbamato groups and one N-bound oxazoline.","PeriodicalId":7796,"journal":{"name":"Analytical Sciences: X-ray Structure Analysis Online","volume":"34 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2008-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytical Sciences: X-ray Structure Analysis Online","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2116/ANALSCIX.24.X155","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3
Abstract
The title material was synthesised by the treatment of [Zn{S2CN(Et)(Ph)}2]2 with excess 2-ethyl-2-oxazoline. The crystal system is triclinic (space group P1 and Z = 2). The unit-cell dimensions are a = 10.2310(4)A, b = 11.4701(5)A, c = 12.1981(5)A with α = 85.952(1)°, β = 75.174(1)°, γ = 72.442(1)° and V = 1319.30(9)A3. The final R value is 0.0248 (4641 observed reflections: I > 2σ(I)). The Zn atom coordinates with two chelating dithiocarbamato groups and one N-bound oxazoline.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
