Structural and optical analysis of nanostructural CuCrO3 perovskite by sol–gel method

K. Batool, M. Rani, R. Shafique, R. Neffati, Mariam Akram, M. Arshad
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Abstract

Abstract CuCrO3 perovskite structure synthesized via cost-effective sol–gel method successfully as confirmed by X-ray diffraction (XRD) with smaller crystallite size has been reported. EDS confirmed copper chromite perovskite single phase with no extra impurity peak existence. Agglomerated grains resulting average particle size of 9.6 nm as determined from SEM micrographs. PL spectra shows electron transition from VB to CB whereas Raman spectra shows D and G band presence within spectra pointing towards existence of functional groups within structure. Bandgap value of 4.02 eV is calculated from UV–vis spectra. In order to calculate Eu, which is calculated to be 0.960 Ev. All these properties suggested synthesized material applicability as an optoelectronic perovskite material.
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溶胶-凝胶法制备纳米结构CuCrO3钙钛矿的结构与光学分析
摘要采用溶胶-凝胶法成功合成了CuCrO3钙钛矿结构,并经x射线衍射(XRD)证实,其晶体尺寸较小。EDS证实铜铬铁矿钙钛矿单相不存在额外的杂质峰。从SEM显微照片中可以看出,颗粒凝聚形成的平均粒径为9.6 nm。PL光谱显示电子从VB跃迁到CB,而拉曼光谱显示D和G波段的存在,表明结构中存在官能团。根据紫外可见光谱计算出带隙值为4.02 eV。为了计算Eu,它被计算为0.960 Ev。所有这些特性表明了合成材料作为光电钙钛矿材料的适用性。
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