{"title":"Infrared intensity measurements—I. Experimental conditions and a standard band","authors":"J.T. Shimozawa , M.K. Wilson","doi":"10.1016/0371-1951(66)80159-5","DOIUrl":null,"url":null,"abstract":"<div><p>The experimental conditions for the measurement of absolute infrared intensities of vibrational transitions have been examined using the out-of-plane CH vibration of 1,2,4,5-tetrachlorobenzone. This symmetrical band has been investigated in solution in carbon disulfide. The band was analyzed by the band shape moment analysis. The error in the experimentally determined intensity is estimated to be ±5 percent. It is suggested that this band would be useful as an intensity standard in condensed systems.</p></div>","PeriodicalId":101180,"journal":{"name":"Spectrochimica Acta","volume":"22 9","pages":"Pages 1591-1597"},"PeriodicalIF":0.0000,"publicationDate":"1966-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0371-1951(66)80159-5","citationCount":"10","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica Acta","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0371195166801595","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 10
Abstract
The experimental conditions for the measurement of absolute infrared intensities of vibrational transitions have been examined using the out-of-plane CH vibration of 1,2,4,5-tetrachlorobenzone. This symmetrical band has been investigated in solution in carbon disulfide. The band was analyzed by the band shape moment analysis. The error in the experimentally determined intensity is estimated to be ±5 percent. It is suggested that this band would be useful as an intensity standard in condensed systems.
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