Colorization of 1-D photonic crystals with Rare-earth element doping

O. Keskin, N. Funda Ak Azem, I. Birlik, R. Dalmış
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Abstract

Nowadays, nature-inspired structural colorization takes increasing attention due to its exceptional optical properties. One-dimensional (1-D) photonic crystals are new kind of optical materials which can be used to obtain structural colorization. In recent years many studies carried out about 1-D photonic crystals because of its simplicity and cost effectiveness. In this study, CuO/TiO2 multilayer thin films were prepared by the sol-gel spin coating technique on the boron silicate substrate. To understand the effect of rare-earth element doping on structural colorization, Cerium and Europium ions doped CuO layers were prepared with different dopant concentrations. Structural and morphological properties of 1-D photonic crystals were investigated by Xray diffraction (XRD), Scanning electron microscopy (SEM) and optical microscopy. Obtained results show that CuO/TiO2 multilayer thin films with different Cerium and Europium concentrations were successfully prepared. Additionally, red and green colorization was achieved with different type and concentrations of dopant elements and more vivid colors were obtained as a result of the increment in dopant concentration.
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稀土元素掺杂一维光子晶体的着色研究
如今,受自然启发的结构着色由于其特殊的光学特性而受到越来越多的关注。一维光子晶体是一种可以实现结构着色的新型光学材料。由于一维光子晶体的简单性和成本效益,近年来进行了大量的研究。在本研究中,采用溶胶-凝胶自旋镀膜技术在硅酸硼基底上制备了CuO/TiO2多层薄膜。为了了解稀土元素掺杂对结构着色的影响,制备了不同掺杂浓度的铈和铕离子掺杂CuO层。利用x射线衍射(XRD)、扫描电子显微镜(SEM)和光学显微镜研究了一维光子晶体的结构和形态特性。结果表明,成功制备了不同铈、铕浓度的CuO/TiO2多层薄膜。此外,不同类型和浓度的掺杂元素可以实现红色和绿色的显色,并且由于掺杂元素浓度的增加而获得更鲜艳的颜色。
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