Prediction of Optimum Process Parameters for Karanja Biodiesel Production using Support Vector Machine, Genetic Algorithm and Particle Swarm Optimization

IF 1 4区 工程技术 Q4 CHEMISTRY, MULTIDISCIPLINARY Iranian Journal of Chemistry & Chemical Engineering-international English Edition Pub Date : 2021-08-07 DOI:10.30492/IJCCE.2021.128278.4153
S. Sastry
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Abstract

The growing energy demand and depletion of the conventional energy resources presented a need for alternative reliable source of energy that can readily replace the conventional fuels like diesel and petrol. In the current work, biodiesel is synthesized from Karanja oil by using transesterification. The yield is obtained at varying KOH concentrations (1 wt %, 1.5 wt %, 2 wt %), varying molar ratios of methanol:oil (3:1, 4.5:1, 6:1) and varying times (15 min, 30 min, 45 min, 60 min). The optimal conditions from experiment are obtained as temperature of 50° C, reaction time of 45 minutes, methanol-oil ratio of 4.5:1 and catalyst concentration of 1.5 %. The viscosity of biodiesel is found to be between 0.036 - 0.038 stokes. Optimum conditions obtained were compared with the statistics available in literature. The produced biodiesel from Karanja oil conform to the ASTM D6751 standards. The produced biodiesel is characterized using Fourier Transform Infra Red (FTIR) Analysis and Gas Chromatography Mass Spectrometry (GC-MS). Further Artificial Intelligence techniques namely Support Vector Machine, Genetic Algorithm and Particle Swarm Optimization have been used for predicting the optimum conditions of the biodiesel production. The predicted yield with Support Vector Machine is compared with yield obtained from experiments. The SVM accurately predicted the experimental results with the R2 = 0.999. PSO and GA can effectively be used as a tool for predicting the optimum parameters for biodiesel production.
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基于支持向量机、遗传算法和粒子群优化的Karanja生物柴油生产最佳工艺参数预测
日益增长的能源需求和传统能源的枯竭提出了一种可替代的可靠能源的需求,这种能源可以很容易地取代柴油和汽油等传统燃料。在目前的工作中,以Karanja油为原料,采用酯交换法合成了生物柴油。在不同的KOH浓度(1wt %, 1.5 wt %, 2wt %),不同的甲醇:油的摩尔比(3:1,4.5:1,6:1)和不同的时间(15分钟,30分钟,45分钟,60分钟)下获得产率。实验得到最佳工艺条件为温度50℃,反应时间45 min,甲醇油比4.5:1,催化剂浓度1.5%。生物柴油的粘度在0.036 - 0.038斯托克之间。将得到的最佳条件与文献统计数据进行比较。从Karanja油生产的生物柴油符合ASTM D6751标准。利用傅里叶变换红外(FTIR)分析和气相色谱-质谱(GC-MS)对制备的生物柴油进行了表征。进一步的人工智能技术,即支持向量机,遗传算法和粒子群优化已被用于预测生物柴油生产的最佳条件。将支持向量机的预测产率与实验产率进行了比较。SVM准确预测实验结果,R2 = 0.999。粒子群算法和遗传算法可以有效地作为预测生物柴油生产最优参数的工具。
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来源期刊
CiteScore
2.80
自引率
22.20%
发文量
0
审稿时长
6-12 weeks
期刊介绍: The aim of the Iranian Journal of Chemistry and Chemical Engineering is to foster the growth of educational, scientific and Industrial Research activities among chemists and chemical engineers and to provide a medium for mutual communication and relations between Iranian academia and the industry on the one hand, and the world the scientific community on the other.
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