{"title":"Efficiency of Ceric Ions of Oxidation and Polymerization—A Review","authors":"S. Nagarajan, K. Srinivasan","doi":"10.1080/15583729808545777","DOIUrl":null,"url":null,"abstract":"Cerium(IV) ions are versatile reagents for the oxidation of numerous functional groups in organic synthesis, as well as in transition metal chemistry. They are also employed [1] to achieve nitration, hydroxylation, rearrangement, addition of carbonyl compounds to 1, 3-dienes, hemolytic malonylation of aromatic hydrocarbons, alkoxyiodination, nitratoiodination, and more. Most of these transformations open up a broad applicability due to their mild reaction conditions, fast conversions, and convenient work-up procedures.","PeriodicalId":16139,"journal":{"name":"Journal of Macromolecular Science-reviews in Macromolecular Chemistry and Physics","volume":"17 1","pages":"53-76"},"PeriodicalIF":0.0000,"publicationDate":"1998-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"8","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Macromolecular Science-reviews in Macromolecular Chemistry and Physics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15583729808545777","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 8
Abstract
Cerium(IV) ions are versatile reagents for the oxidation of numerous functional groups in organic synthesis, as well as in transition metal chemistry. They are also employed [1] to achieve nitration, hydroxylation, rearrangement, addition of carbonyl compounds to 1, 3-dienes, hemolytic malonylation of aromatic hydrocarbons, alkoxyiodination, nitratoiodination, and more. Most of these transformations open up a broad applicability due to their mild reaction conditions, fast conversions, and convenient work-up procedures.