Mechanism of low thermal conductivity of xonotlite-silica aerogel nanoporous super insulation material

Hailong Yang, Wen Ni, Deping Chen, Guoqiang Xu, Tao Liang, Li Xu
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引用次数: 7

Abstract

In an effort to incorporate the low thermal conductivity of the silica aerogel and the superior structure strength of the xonotlite, a composite material of these two was produced. It was synthesized under vacuum condition and dried by supercritical drying technique. The thermal conductivity of the new material, which is at 298 K with the gas pressure ranging from 1.01×105 to 1×102 Pa, was measured using the transient hot-strip method. The mechanism of the low thermal conductivity was studied. The results indicate that the low thermal conductivity mainly results from the significant decrease of gaseous thermal conductivity of the new material due to the restriction of the motion of gas molecules in its fine structures. The formation of the fine structures is because the new material takes the pore structure of the silica aerogel which consists of mainly nanometer-sized pores. © 2008 University of Science and Technology Beijing. All rights reserved.

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硅钙石-气凝胶纳米多孔超保温材料的低导热机理
为了结合二氧化硅气凝胶的低导热性和硅钙石的优越结构强度,生产了一种将两者结合起来的复合材料。在真空条件下合成并采用超临界干燥技术进行干燥。采用瞬态热带法测量了该材料的热导率,其温度为298 K,气体压力范围为1.01×105 ~ 1×10−2 Pa。对低导热的机理进行了研究。结果表明,新材料的热导率低主要是由于其精细结构中气体分子的运动受到限制,导致气体热导率显著降低。细结构的形成是由于新材料采用了二氧化硅气凝胶的孔隙结构,主要由纳米级孔隙组成。©2008北京科技大学版权所有。
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