{"title":"Etude de la radiolyse du pentane normal a 77 K par capture des radicaux apres l'irradiation","authors":"J. Allaert, P. Claes, B. Tilquin","doi":"10.1016/0020-7055(76)90086-3","DOIUrl":null,"url":null,"abstract":"<div><p><em>n</em>-Pentane was irradiated in the solid phase at 77 K. Post-irradiation scavenging of radicals by dissolving at 110 K the irradiated pentane in a propane-oxygen mixture lowers the decanes and pentenes <em>G</em>-values to an extent of 40–60%. The principal experimental results are: (1) a radical <em>G</em>-value of 2·76; (2) a radicalar distribution of 30% in primary radicals and 70% in secondary radicals; (3) a rough dismutation-combination ratio of 2·1 at 120 K.</p></div>","PeriodicalId":100688,"journal":{"name":"International Journal for Radiation Physics and Chemistry","volume":"8 3","pages":"Pages 387-390"},"PeriodicalIF":0.0000,"publicationDate":"1976-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-7055(76)90086-3","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal for Radiation Physics and Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020705576900863","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3
Abstract
n-Pentane was irradiated in the solid phase at 77 K. Post-irradiation scavenging of radicals by dissolving at 110 K the irradiated pentane in a propane-oxygen mixture lowers the decanes and pentenes G-values to an extent of 40–60%. The principal experimental results are: (1) a radical G-value of 2·76; (2) a radicalar distribution of 30% in primary radicals and 70% in secondary radicals; (3) a rough dismutation-combination ratio of 2·1 at 120 K.
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