PREPARATION OF NOVEL CERIUM PHOSPHATE WHITE PIGMENT

H. Onoda, H. Muraki
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Abstract

Catalytically active cerium dioxide is used as light reflection materials for cosmetic applications. Therefore, cosmetics containing this pigment cause oxidation of the skin. From this fact, the substitute for cerium dioxide is required to prepare the cosmetics without catalytic activity. Herein, as novel white pigments for use in cosmetics, cerium phosphate was prepared at various pH values. The chemical composition, powder properties, catalytic activity, color, and smoothness of the cerium phosphate were evaluated. All samples prepared in this work indicated XRD pattern of the cerium phosphate hydrate. The sample prepared at pH 4 had relatively small particles and low static friction resistance. The samples prepared at pH 5, 6, and 7 had no photocatalytic activity. The samples prepared at pH 5 and 6 exhibited high reflectance within the range of visible light. (Received Nov 20, 2018; Accepted Dec 17, 2018)
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新型磷酸铈白色颜料的制备
催化活性二氧化铈被用作化妆品应用的光反射材料。因此,含有这种色素的化妆品会引起皮肤氧化。因此,需要二氧化铈的替代品来制备无催化活性的化妆品。本文以磷酸铈为研究对象,在不同的pH值下制备了新型的化妆品用白色颜料。对磷酸铈的化学成分、粉末性能、催化活性、颜色和光滑度进行了评价。所制备的样品均具有磷酸铈水合物的XRD谱图。在pH值为4时制备的样品颗粒较小,静摩擦阻力低。在pH值为5、6和7时制备的样品没有光催化活性。在pH为5和6的条件下制备的样品在可见光范围内具有较高的反射率。(收稿日期:2018年11月20日;接受2018年12月17日)
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PREPARATION OF SILICON-SUBSTITUTED BETA-TRICALCIUM PHOSPHATE BY THE POLYMERIZED COMPLEX METHOD PHOTODEGRADATION OF DYES IN THE PRESENCE OF BISMUTH-TREATED APATITES AS HETEROGENEOUS CATALYSTS IN WATER KEY FACTORS FOR THE SEPARATION OF SILICON AND IRON DURING PHOSPHORUS RECOVERY FROM SLAG DISCHARGED FROM THE DOUBLE-SLAG REFINING PROCESS ION RELEASE BEHAVIOR OF SILICOPHOSPHATE GLASSES CONTAINING SIX-FOLD COORDINATED SILICON STRUCTURE PHOSPHORUS RECOVERY FROM SEWAGE-SLUDGE MOLTEN SLAG USING A COMBINATION OF ACID-DISSOLUTION, ALKALI-PRECIPITATION, AND ION-EXCHANGE
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