Effect of Halide Ion in the Perovskite on Perovskite Solar Cell Performances

Sarith Sankalpa Ranasinghe, Yehan Laknath Kuruppu, G. Sewvandi
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Abstract

In this paper, a p-i-n perovskite solar cell was studied using Solar Cell Capacitance Simulator (SCAPS). A perovskite solar cell with MAPbI3 and a perovskite solar cell with MAPbBr3 as the light-absorbing materials have been simulated and compared the effect of the halide ion on solar cell performances. The efficiency of MAPbI3 and MAPbBr3 were reached 16.8% and 5.14% respectively. Also, the thickness of each MAPbI3 and MAPbBr3 was varied from $0.1\ \mu\mathrm{m}$ to $1.2\ \mu\mathrm{m}$ and the best results were observed at $0.5\ \mu\mathrm{m}$ and $0.4\ \mu\mathrm{m}$ thickness of MAPbI3 and MAPbBr3 films, respectively. A considerable effect of halide ions on perovskite solar cell performances can be attributed to the variation of light absorption with the halide ions.
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钙钛矿中卤化物离子对钙钛矿太阳能电池性能的影响
本文利用太阳能电池电容模拟器(SCAPS)对钙钛矿太阳能电池进行了研究。模拟了以MAPbI3为吸光材料的钙钛矿太阳能电池和以MAPbBr3为吸光材料的钙钛矿太阳能电池,并比较了卤化物离子对太阳能电池性能的影响。MAPbI3和MAPbBr3的效率分别达到16.8%和5.14%。MAPbI3和MAPbBr3薄膜的厚度在$0.1\ \mu\mathrm{m}$到$1.2\ \mu\mathrm{m}$之间变化,在$0.5\ \mu\mathrm{m}$和$0.4\ \mu\mathrm{m}$时效果最好。卤化物离子对钙钛矿太阳能电池性能的显著影响可归因于光吸收随卤化物离子的变化。
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