Surface plasmon resonance research on photoinduced switch properties of liquid crystalline azobenzene polymer Langmuir–Blodgett films

Jianhua Gu, Hua Lü, Lingyun Liu, Bingjie Liang, Yiwen Chen, Zuhong Lu
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引用次数: 6

Abstract

We report a novel phenomenon of photoisomerization-induced switch properties in liquid crystalline azo-benzene polymer poly{2-hydroetheyl methacrylate}-co-{6-[4-(S-2-methyl-1-butyloxycarbonylphenylazo) phenoxy]hexyl methacrylate} Langmuir–Blodgett (LB) monolayers. These monolayers were deposited on gold film and irradiated with UV (360 nm) and blue (450 nm) light. The switch properties were investigated by the surface plasmon resonance (SPR) technique. A method called photoinduced patterning was used for the fabrication of a model molecular device. It has been found that the photoinduced process of writing and erasing in such devices can be repeated for tens of cycles.

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液晶偶氮苯聚合物Langmuir-Blodgett薄膜光致开关特性的表面等离子体共振研究
我们报道了液晶偶氮苯聚合物聚{2-甲基丙烯酸氢乙酯}-co-{6-[4-(s -2-甲基-1-丁基羰基苯基偶氮)苯氧基]甲基丙烯酸己基}Langmuir-Blodgett (LB)单层中光异构化诱导开关性质的新现象。将这些单层膜沉积在金膜上,用紫外光(360 nm)和蓝光(450 nm)照射。利用表面等离子体共振(SPR)技术研究了其开关特性。一种称为光诱导图案化的方法被用于制造模型分子器件。人们已经发现,在这种器件中,光诱导的写入和擦除过程可以重复几十个周期。
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