Thermal Dissolution of Bituminous Coal in Heavy Coal Semicoking Tar and in Binary Blends with the Anthracene Oil

P. N. Kuznetsov, B. Avid, X. Fan, N. V. Perminov, L. I. Kuznetsova, I. V. Korolkova
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Abstract

The effect of hydrorefining of heavy coal semicoking tar on its composition and efficiency for bituminous coal dissolution was studied. It was found that the concentration of the oxygen-bearing compounds decreased as a result of catalytic hydrotreating with hydrogen or with hydrogen donors. This resulted in improved dissolving power. However, best result in coal dissolution was achieved when heavy semicoking tar was blended with the anthracene oil. The products obtained represented at ambient temperature solid pitch-like matter with the softening points of 124 to 138 °С (“ring and ball” method). It was composed of mainly bi- and three-cyclic aromatics, the content of quinoline-insolubles being less than 6 %, and the ash content less than 0.5 %
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烟煤在重煤半焦焦油和与蒽油二元共混物中的热溶解
研究了重煤半焦焦油加氢精制对其组成及对烟煤溶出效率的影响。结果表明,用氢或用氢供体催化加氢处理后,含氧化合物的浓度降低。这提高了溶解力。然而,当重质半焦焦油与蒽油混合时,煤的溶解效果最好。所得产物为常温下的固体类沥青物质,软化点为124 ~ 138°С(“环球法”)。主要由双环芳烃和三环芳烃组成,喹啉不溶物含量小于6%,灰分含量小于0.5%
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