V. Romanenko, V. L. Rudzevich, E. Rusanov, A. N. Chernega, A. Senio, J. Sotiropoulos, G. Pfister-guillouzo, Michel Sanchez
{"title":"Synthesis and structural characterization of the first donor-stabilized phosphanetriylphosphonium cation: [Ar*PP(PPh3)]+(Ar*= 2,4,6-But3C6H2)","authors":"V. Romanenko, V. L. Rudzevich, E. Rusanov, A. N. Chernega, A. Senio, J. Sotiropoulos, G. Pfister-guillouzo, Michel Sanchez","doi":"10.1039/C39950001383","DOIUrl":null,"url":null,"abstract":"Reaction of Ar*PPNR2(Ar*= 2,4,6-But3C6H2) with CF3SO3H in the presence of triphenylphosphane in CH2Cl2produces the isolable salt [Ar*PP(PPh3)]+[CF3SO3]– which is characterized by X-ray crystallography; the triphenylphosphane ligand of [Ar*PP(PPh3)]+ readily participates in nucleophilic substitution reactions affording a novel entry to donor-stabilized phosphanetriylphosphonium cations and P-functionalized diphosphenes.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"2 1","pages":"1383-1385"},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"22","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950001383","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 22
Abstract
Reaction of Ar*PPNR2(Ar*= 2,4,6-But3C6H2) with CF3SO3H in the presence of triphenylphosphane in CH2Cl2produces the isolable salt [Ar*PP(PPh3)]+[CF3SO3]– which is characterized by X-ray crystallography; the triphenylphosphane ligand of [Ar*PP(PPh3)]+ readily participates in nucleophilic substitution reactions affording a novel entry to donor-stabilized phosphanetriylphosphonium cations and P-functionalized diphosphenes.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
