Sub-microns NaCl-TiO2 Particles to Improve the Rain Enhancement as Cloud Seeding

RAN Pub Date : 2017-04-01 DOI:10.11159/ICNEI17.105
N. E. Hadri, A. Zaki, M. Vargas, L. Zou, M. Jouiad
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引用次数: 1

Abstract

Extended Abstract The water scarcity in the arid region is a real concern to consider in near future. For instance, the United Arab Emirates accounts for 110 mm as the average annual rainfall, which is restricting the abundance of groundwater originating from the rainfall. Hence, there is an urgent need to look for an alternative to increase water levels to satisfy the continual growth of human and industrial needs. A promising alternative that becomes more achievable due the late technologies development is the use of cloud seeding particles to enhance the rainfall [1]. Indeed, cloud seeding is a process that allows altering the weather by the insertion of a material into the clouds in order to trigger the formation and the growth of droplets, once the water droplets are big enough they will fall due to gravity participating in the enhancement of rainfall. Basically, clouds are composed of dust particles and condensed water and the thermodynamic conditions for the formation of the droplets happened with the nucleation by aerosol particles [2]. There are two cloud seeding methods: hygroscopic cloud seeding and glaciogenic cloud seeding. In hygroscopic cloud seeding (warm clouds), it implicates the addition of salt crystals to attract water droplets and promote collision-coalescence process to form bigger droplets [3]. In glaciogenic seeding (cold clouds), it implicates the addition of particles to the cool clouds (water is below the freezing point) in order to form ice crystals, which will grow and fall. Silver iodide is used for glaciogenic cloud seeding because its form is similar to ice crystals. In this present study, new nanomaterials were used in order to obtain a high performance for hygroscopic cloud seeding. Optimized NaCl cubic crystals with a size of 1 μm were used to prepare sub-micron NaCl/TiO2. The NaCl/TiO2 were evaluated by using scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction, Raman spectroscopy and water vapor sorption. SEM will be used in order to observe the shape and the size of the NaCl and NaCl/TiO2 particles. TEM, XRD and Raman were used in order to make in evidence the presence of the TiO2 coating on the NaCl salt crystals surface. Figure 1 gives the SEM image of the composite crystals used in this study. They have cubic like shape.
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亚微米NaCl-TiO2粒子在人工增雨中的应用
干旱地区的水资源短缺问题在不久的将来是一个值得关注的问题。例如,阿联酋的年平均降雨量为110毫米,这限制了降雨产生的地下水的丰富程度。因此,迫切需要寻找一种替代方案来增加水位,以满足人类和工业需求的持续增长。由于后期技术的发展,一种有希望的替代方案变得更容易实现,即使用云播粒子来增强降雨[1]。事实上,云播是一种通过在云中插入一种物质来改变天气的过程,以触发水滴的形成和增长,一旦水滴足够大,它们就会由于重力参与降雨的增强而下降。云基本上是由尘粒和凝结水组成的,液滴形成的热力学条件是伴随着气溶胶粒子的成核而发生的[2]。有两种播云方法:吸湿性播云和冰川性播云。在吸湿云(暖云)中,通过添加盐晶体来吸引水滴,促进碰撞聚结过程,形成更大的水滴[3]。在冰期播种(冷云)中,它意味着向冷云(水在冰点以下)中添加粒子,以形成冰晶,冰晶会生长和下降。碘化银因其形态与冰晶相似而被用于冰期造云。在本研究中,为了获得高性能的吸湿云播种,使用了新型纳米材料。采用优化后尺寸为1 μm的NaCl立方晶体制备亚微米NaCl/TiO2。采用扫描电镜(SEM)、透射电镜(TEM)、x射线衍射(xrd)、拉曼光谱(Raman spectroscopy)和水蒸气吸附(water vapor absorption)对NaCl/TiO2进行了表征。利用扫描电镜观察NaCl和NaCl/TiO2颗粒的形状和大小。利用透射电镜、XRD和拉曼光谱等手段证实了TiO2涂层在NaCl盐晶体表面的存在。图1给出了本研究中使用的复合晶体的SEM图像。它们有立方体的形状。
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