NANOCOATING OF POLYESTER FABRIC WITH GRAPHENE OXIDE

Beyza Doğan, Ş. Uğur, Banu Esencan Turkaslan
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Abstract

GO is easily dispersed in solvents, dielectric property, transparency, electronic features can be adjusted due to the superior mechanical properties and areas of use are expanding day by day. In this study, graphene oxide was obtained from graphite by using modified Hummers method and then applied to polyester fabric surface according to multilayer coating method. Contrary to the traditional Hummers method in the literature, this study was carried out without the use of NaNO₃ in order to be environmentally friendly. Based on the Layer-by-Layer coating method, GO based nano films have been applied to the polyester fabric surface. After obtaining the GO based nanocomposite polyester fabrics, it was treated with Na₂S₂O₄ and NaBH₄ in order to obtain RGO structure and GO reduction was achieved. A thin coating layer was observed in SEM analysis of the reduced graphene oxide (RGO) and GO coated fabrics. In the EDS analysis, increase in the amount of C and the decrease in the amount of O were determined after the reduction process. The most striking feature of graphene oxide was applied to all fabrics with a 4-probe measuring device and the best result was observed in the polyester fabric which was coated with Na₂S₂O₄ in 10 layer 5 minutes with Layer-by-Layer coating method with 1.47 × 1̄0 ³ S/cm².
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氧化石墨烯纳米涂层在聚酯织物中的应用
氧化石墨烯易分散于溶剂中,介电性能、透明度、电子特性均可调节,因其优越的机械性能和使用领域正日益扩大。本研究以石墨为原料,采用改进的Hummers法制备氧化石墨烯,然后采用多层涂覆法将氧化石墨烯涂覆在涤纶织物表面。与文献中传统的Hummers方法相反,为了环保,这项研究没有使用NaNO₃。基于逐层涂布的方法,将氧化石墨烯基纳米薄膜应用于涤纶织物表面。得到氧化石墨烯基纳米复合涤纶织物后,用Na₂S₂O₄和NaBH₄对其进行处理,得到还原氧化石墨烯结构,实现了氧化石墨烯还原。SEM分析发现,还原氧化石墨烯(RGO)和氧化石墨烯涂层织物表面有一层薄薄的涂层。在EDS分析中,测定了还原过程后C的量增加,O的量减少。利用4探针测量装置将氧化石墨烯最显著的特征应用到所有织物上,采用逐层涂布法,在105min内涂布Na₂S₂O₄,涂布效果最佳,涂布率为1.47 × 1′0³S/cm²。
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