Modification of accelerated thermal stabilization of polyacrylonitrile fibers by creating an oxygen concentration gradient in the production of carbon fiber

Abstract

Objectives. The work set out to modify the technology of accelerated thermal stabilization of polyacrylonitrile (PAN) fibers used in the production of high-strength carbon fibers by reducing the formation of a heterophase core–shell structure to create an oxygen concentration gradient in heat treatment furnaces while maintaining a total thermal stabilization time of 30 min. The optimized process conditions led to milder thermal stabilization conditions, reducing both the final heat treatment temperature and the temperature difference between the thermal stabilization zones while simultaneously maintaining the target volume density parameter with respect to the previously developed accelerated thermal stabilization technology.Methods. The thermal stabilization study of an industrially produced 12S precursor under different conditions on an experimental carbon fiber production line included measurement of bulk density, analysis of the thermal effects of the oxidation reaction by differential scanning calorimetry (DSC), and a study of micrographs of the resulting samples.Results. The optimum process of thermal stabilization of PAN fiber was determined in four stabilization zones using selected compositions. The formation of the core–shell structure is significantly reduced when the target volume density and DSC thermal oxidation reaction effect of the stabilized polymer fiber are achieved in a given time (30 min).Conclusions. The resulting technology regime is promising for the production of high strength (4.5 GPa, 4.9 GPa) PAN fibers at a reduced cost. While maintaining the total thermal stabilization time of PAN at the level of 30 min, which is three times less than the industrial processes used, it was possible to reduce the formation of a heterophase structure, as well as lowering the final processing temperature and reducing the temperature difference between the stabilization zones. This is promising in terms of a positive effect on the stability and safety of the industrial process, as well as ensuring the quality of the obtained products.