Study the Effect of Graphene on the Contact Angle, Water Absorption and Thermal Stability ( TGA ,DSC) for Blend (Epoxy & Repcoat ZR)

M. M. Hassin, Seenaa I. Hussein
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Abstract

In this study, polymeric coating was developed by incorporating nano graphene in the polymer blend with applications to oil storage tanks. The oil storage tanks samples were brought from the oil Pipeline Company / Doura refinery in Baghdad. The coating polymer was formed with a blend (epoxy resin and repcoat ZR). The proportion of mixing the mixture was 3:1:1 epoxy resin 21.06 gm: repcoat ZR 10.53 gm: hardener 10.53 gm. The blend/graphene was prepared using in stui-polymerization method with different weight percentage 1, 3, 5, and 7 wt % added to blend. The resulting solution was put in a glass tube on a magnetic stirrer for one hour at a temperature of 40 °C. The result of contact angle and water absorption the best ratio of 3wt % (73.46). The current work confirms that the thermal stability of the nanocomposites increases gradually with increasing the percentage of Gr compared to the blend without adding Gr nano and this is due to the thermal resistance of the Gr nano.
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石墨烯对环氧复合涂料ZR共混物接触角、吸水性和热稳定性(TGA、DSC)的影响
在本研究中,通过在聚合物共混物中加入纳米石墨烯,开发了聚合物涂层,并将其应用于储油罐。储油罐样品是从巴格达的输油管道公司/杜拉炼油厂运来的。涂层聚合物由环氧树脂与复涂剂ZR共混而成。混合比例为3:1:1:环氧树脂21.06 gm:复涂剂ZR 10.53 gm:硬化剂10.53 gm。采用单聚法制备共混物/石墨烯,共混物中加入不同重量百分比1、3、5、7 wt %。将得到的溶液放入玻璃管中,在磁力搅拌器上,在40°C的温度下搅拌1小时。结果接触角与吸水率的最佳比值为3wt %(73.46)。目前的研究证实,与未添加纳米Gr的共混物相比,随着纳米Gr含量的增加,纳米复合材料的热稳定性逐渐提高,这是由于纳米Gr的热阻。
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