Development of Cordierite Based Carrier Refractory Sagar Bodies for Bone Porcelain Firing Process

Murat Ispalarli, Zuhal Karaağaç
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Abstract

During the firing process of porcelain tableware; Biscuit firing takes place at low temperatures (980-1000°C), while glazed firing takes place at high temperatures (1250-1280°C for soft porcelain, 1350-1380°C for hard porcelain). Biscuit firing in bone porcelain products, which is in the soft porcelain class, is done at higher temperatures than glazed firings. Due to the presence of bone ash in the Bone China recipe formulation, it causes the bodies to undergo vitrification in a narrow range and thus the final product to deform during sintering. Bone porcelain products are fired on carrier refractories called sagar so that they do not deform during sintering. Sagars are designed to support that model for each product model and do not shrink or deform during firing thanks to its low thermal expansion coefficient. In this study, a refractory body with a porous structure with the code of "PS1-Std" was developed by performing the characterization analyzes of refractory products with different technical properties supplied from different companies. In order to improve the mechanical properties by changing the ratios of talc, alumina, quartz and zircon in the recipe composition; A refractory product containing 8.47% zircon in its recipe composition and containing indialite, corundum, mullite, quartz and zircon phases after sintering has been developed. The microstructure images of the developed refractory product were examined with the support of SEM analysis. It has been observed that refractory products obtained as a result of recipe development studies offer a 10% longer service life than equivalent refractory products.
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骨瓷烧制用堇青石基载体耐火Sagar体的研制
陶瓷餐具在烧制过程中;饼干烧制在低温下进行(980-1000°C),而釉面烧制在高温下进行(软瓷1250-1280°C,硬瓷1350-1380°C)。骨瓷产品的饼干烧制属于软瓷类,比釉面烧制的温度更高。由于骨瓷配方配方中存在骨灰,它会导致瓷体在很小的范围内发生玻璃化,从而导致最终产品在烧结过程中变形。骨瓷制品是在称为sagar的载体耐火材料上烧制的,因此它们在烧结过程中不会变形。Sagars设计用于支持每种产品型号的模型,并且由于其热膨胀系数低,在点火过程中不会收缩或变形。在本研究中,通过对不同公司提供的不同技术性能的耐火材料进行表征分析,开发了一个具有多孔结构的耐火材料体,代码为“PS1-Std”。通过改变配方组成中滑石、氧化铝、石英和锆石的比例来改善其力学性能;研制出配方成分中锆石含量为8.47%,烧结后含有独长石、刚玉、莫来石、石英和锆石相的耐火产品。利用扫描电镜对所研制的耐火材料的微观结构进行了分析。据观察,由于配方开发研究而获得的耐火材料产品比同等耐火材料产品的使用寿命长10%。
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