{"title":"Intramolecular dynamics of [Rh4(CO)6(μ-PPh2)4] in solution","authors":"E. Gullo, S. Detti, G. Laurenczy, R. Roulet","doi":"10.1039/B208318C","DOIUrl":null,"url":null,"abstract":"A 103Rh, 31P and 13C NMR study of [Rh4(CO)6(μ-PPh2)4] in CD2Cl2 indicates that the strongly bonded, bridging, anionic ligand PPh2− takes part in the site exchange of the carbonyl ligands and is actually mobile about the metallic surface of this cluster compound.","PeriodicalId":17317,"journal":{"name":"Journal of The Chemical Society-dalton Transactions","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2002-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society-dalton Transactions","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/B208318C","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 4
Abstract
A 103Rh, 31P and 13C NMR study of [Rh4(CO)6(μ-PPh2)4] in CD2Cl2 indicates that the strongly bonded, bridging, anionic ligand PPh2− takes part in the site exchange of the carbonyl ligands and is actually mobile about the metallic surface of this cluster compound.
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