{"title":"Pyrolysis effects on the reactions of alkoxide anions","authors":"Geneviève Boand, Raymond Houriet, Tino Gäumann","doi":"10.1016/0020-7381(83)85093-1","DOIUrl":null,"url":null,"abstract":"<div><p>The distribution of products in negative chemical-ionization spectra of alcohols are shown to remain unaffected (<1%) by pyrolytic reactions. On the other hand, it is shown that slow ion/molecule reactions can be obscured by fast processes implying impurities formed by pyrolysis. The importance of pumping speed in ion cyclotron resonance (ICR) spectrometers is also discussed.</p></div>","PeriodicalId":13998,"journal":{"name":"International Journal of Mass Spectrometry and Ion Physics","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1983-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-7381(83)85093-1","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Mass Spectrometry and Ion Physics","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020738183850931","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
Abstract
The distribution of products in negative chemical-ionization spectra of alcohols are shown to remain unaffected (<1%) by pyrolytic reactions. On the other hand, it is shown that slow ion/molecule reactions can be obscured by fast processes implying impurities formed by pyrolysis. The importance of pumping speed in ion cyclotron resonance (ICR) spectrometers is also discussed.
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