{"title":"Radiobromination of aromatic compounds by cleavage of aryl-tin bonds","authors":"M.J. Adam, T.J. Ruth, Y. Homma , B.D. Pate","doi":"10.1016/0020-708X(85)90250-9","DOIUrl":null,"url":null,"abstract":"<div><p>Radiobrominated (<sup>77,82</sup>Br) aromatic compounds were synthesized by the cleavage of aryl-tin derivatives with oxidized low specific activity <sup>82</sup>Br or no-carrier-added (NCA) [<sup>77</sup>Br]bromide. Both chloramine-T and N-chlorosuccinimide, when used as oxidants, gave near quantitative yields within 5 min.</p></div>","PeriodicalId":22517,"journal":{"name":"The International journal of applied radiation and isotopes","volume":"36 12","pages":"Pages 935-937"},"PeriodicalIF":0.0000,"publicationDate":"1985-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-708X(85)90250-9","citationCount":"18","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"The International journal of applied radiation and isotopes","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020708X85902509","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 18
Abstract
Radiobrominated (77,82Br) aromatic compounds were synthesized by the cleavage of aryl-tin derivatives with oxidized low specific activity 82Br or no-carrier-added (NCA) [77Br]bromide. Both chloramine-T and N-chlorosuccinimide, when used as oxidants, gave near quantitative yields within 5 min.