Biotribological behavior of ultra high molecular weight polyethylene composites containing bovine bone hydroxyapatite

Jin-long LIU, Yuan-yuan ZHU, Qing-liang WANG, Shi-rong GE
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引用次数: 39

Abstract

Wear particles of ultrahigh molecular weight polyethylene (UHMWPE) are the main cause of long-term failure of total joint replacements. Therefore, increasing its wear resistance or bioactivity will be very useful in order to obtain high quality artificial joints. In our study, UHMWPE composites filled with the bovine bone hydroxyapatite (BHA) were prepared by the method of compression moulding. A ball-on-disc wear test was carried out with a Universal Micro-Tribometer to investigate the friction and wear behavior of a Si3N4 ceramic ball, cross-sliding against the UHMWPE/BHA composites with human plasma lubrication. At the same time, the profiles of the worn grooves on the UHMWPE/BHA surface were scanned. The experimental results indicate that the addition of BHA to UHMWPE had a significant effect on the biotribological behavior of UHMWPE cross-sliding against the Si3N4 ceramic ball. The addition of BHA powder enhanced the hardness and modulus of elasticity of these composites and decreased the friction coefficients and wear rates under conditions of human plasma lubrication. When the added amount of BHA powders was up to 20%∼30%, UHMWPE/BHA composites demonstrated the designed performance of the mechanical properties and biotribological behavior.

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含牛骨羟基磷灰石的超高分子量聚乙烯复合材料的生物摩擦学行为
超高分子量聚乙烯(UHMWPE)磨损颗粒是导致全关节置换术长期失效的主要原因。因此,提高其耐磨性或生物活性对于获得高质量的人工关节是非常有用的。本研究采用压缩模塑法制备了牛骨羟基磷灰石(BHA)填充的超高分子量聚乙烯复合材料。采用通用微摩擦计对Si3N4陶瓷球与UHMWPE/BHA复合材料进行了摩擦磨损试验,研究了Si3N4陶瓷球在人体等离子润滑下与UHMWPE/BHA复合材料的摩擦磨损行为。同时,对UHMWPE/BHA表面磨损槽的轮廓进行了扫描。实验结果表明,在UHMWPE中添加BHA对UHMWPE与Si3N4陶瓷球的交滑生物摩擦学行为有显著影响。在人体等离子润滑条件下,BHA粉末的加入提高了复合材料的硬度和弹性模量,降低了摩擦系数和磨损率。当BHA粉末的添加量达到20% ~ 30%时,UHMWPE/BHA复合材料表现出设计的力学性能和生物摩擦学性能。
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