N. Connelly, David J. H. Emslie, Bernhard Metz, A. Orpen, M. J. Quayle
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引用次数: 24
Abstract
One-electron oxidation of the square-planar, 16-electron complex [Rh(CO)(PPh3)(κ2-Tp′)] with [FeCp2][PF6] gives the square-pyramidal RhII complex [Rh(CO)(PPh3)(κ3-Tp′)][PF6] in which the third pyrazolyl group of Tp′ is N-bound in the axial position by a three-electron two-centre bond (Rh–Naxial 0.13 A longer than Rh–Nbasal).
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