Preparation of a Composite of Copper Oxide Nanoparticles with Carbon by Exploding Graphite Rod in Aqueous Suspension

Sawsan H. Abdulla, H. Humud, F. Mustafa
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Abstract

In this work, the effect of preparing a composite of copper oxide nanoparticles with carbon on some of its optical properties was studied. The composite preparing process was carried out by exploding graphite electrodes in an aqueous suspension of copper oxide. The properties of the plasma which is formed during the explosion were studied using emission spectroscopy in order to determine the most important elements that are present in the media. The electron’s density and their energy, which is the main factor in the composite process, were determined. The particle properties were studied before and after the exploding process. The XRD showed an additional peak in the copper oxides pattern corresponding to the hexagonal graphite structure for the composite. The UV-visible absorbance for the composite was significantly enhanced. The direct bandgap decreased from 2.55 to 2.4 eV, and the indirect bandgap decreased from 1.1 to 1 eV, for the composite.
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水悬浮液中石墨棒爆炸法制备纳米氧化铜-碳复合材料
本文研究了纳米氧化铜与碳复合材料的制备对其光学性能的影响。采用爆炸石墨电极在氧化铜水悬浮液中制备复合材料。用发射光谱法研究了爆炸中形成的等离子体的性质,以便确定介质中存在的最重要的元素。测定了复合过程中影响电子密度和电子能量的主要因素。对爆炸前后的颗粒性质进行了研究。XRD结果表明,复合材料的六方石墨结构在铜氧化物谱图中有一个附加峰。复合材料的紫外可见吸光度明显增强。复合材料的直接带隙从2.55 eV减小到2.4 eV,间接带隙从1.1 eV减小到1 eV。
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