Behavior of radionuclides in the environment—I. Sorption of Zn(II) on clay minerals

Ryoko Fujiyoshi, Andriamisamanana Solofo Eugene, Meiseki Katayama
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引用次数: 16

Abstract

Adsorption of Zn(II) on clay minerals (kaolinite, montmorillonite and bentonite) has been investigated spectrophotometrically and radiometrically. Both techniques offered fairly consistent results in spite that different procedure was used to obtain adsorbed amount of Zn(II). Adsorption isotherms fit Freundlich type equation depending on pH value of each clay suspension. The adsorbed amount of Zn(II) increased with increasing pH value of the suspension. Remarkable effect of Mg(II) on Zn(II) adsorption was observed in the case of bentonite. The results obtained may be explained by considering different surface properties of individual clay minerals.

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放射性核素在环境中的行为i。黏土矿物对Zn(II)的吸附
用分光光度法和辐射光度法研究了锌(II)在粘土矿物(高岭石、蒙脱土和膨润土)上的吸附。尽管采用了不同的方法来获得Zn(II)的吸附量,但两种方法的结果相当一致。吸附等温线与各悬浮液的pH值有关,符合Freundlich型方程。随着悬浮液pH值的增加,Zn(II)的吸附量增加。在膨润土的情况下,Mg(II)对Zn(II)的吸附效果显著。所得结果可以通过考虑不同粘土矿物的不同表面性质来解释。
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