Recent Advances in Acid–Base and Solvation Properties of Metal Phenolates

E. L. Bastos, C. O. Machado
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引用次数: 2

Abstract

This chapter is an update of a recent review on the acid–base chemistry and solvation properties of metal phenolates. After a brief introduction on the physicochemical properties of metal phenolates, the interaction between phenolate ligands and metal Lewis acids is discussed. Examples of solvent effects on the acid–base properties, structure, and chemical reactivity are presented. Furthermore, the interaction of multidentate phenolic ligands and metal cations is highlighted because of their relevance in transition-metal coordination chemistry, catalyst development, metalloenzyme mimicry, cytotoxicity, and magnetic properties. Keywords: metal phenolates; solvent effects; acid–base equilibrium
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金属酚类化合物的酸碱及溶剂化性能研究进展
本章是对金属酚类化合物的酸碱化学和溶剂化性质的最新综述。在简要介绍了金属酚酸酯的物理化学性质后,讨论了酚酸酯配体与金属路易斯酸的相互作用。举例说明溶剂对酸碱性质、结构和化学反应性的影响。此外,多齿酚类配体和金属阳离子的相互作用被强调,因为它们在过渡金属配位化学、催化剂开发、金属酶模拟、细胞毒性和磁性方面具有相关性。关键词:金属酚类;溶剂的影响;酸碱平衡
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