{"title":"Iron(II) and magnesium(II) porphyrin acid solvolysis reactions","authors":"A. Valiotti, A. Adeyemo, P. Hambright","doi":"10.1016/0020-1650(81)80004-9","DOIUrl":null,"url":null,"abstract":"<div><p>Rate = k(M-P)(H<sup>+</sup>)<sup>2</sup> for a Mg<sup>2+</sup> and Fe<sup>2+</sup> water soluble porphyrin acid solvolysis reaction. Such rates parallel Buchler's stability index, S<sub>i</sub>, and the kinetic stability to acid solvolysis of 2+ metal ions is Ni>Cu>Co>Zn>Fe>Mn>Mg>Cd.</p></div>","PeriodicalId":13630,"journal":{"name":"Inorganic and Nuclear Chemistry Letters","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-1650(81)80004-9","citationCount":"6","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic and Nuclear Chemistry Letters","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020165081800049","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 6
Abstract
Rate = k(M-P)(H+)2 for a Mg2+ and Fe2+ water soluble porphyrin acid solvolysis reaction. Such rates parallel Buchler's stability index, Si, and the kinetic stability to acid solvolysis of 2+ metal ions is Ni>Cu>Co>Zn>Fe>Mn>Mg>Cd.
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