Etude en microscopie electronique de la morphologie des depôts electrolytiques de zinc

M. Froment, G. Maurin
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引用次数: 17

Abstract

Zinc electrodeposits prepared in alkaline or acidic media have three successive aspects for increasing currents: spongy, compact and dendritic. This sequence is in good agreement with some recent electrochemical kinetic studies which predict, in peculiar conditions, a current distribution on the surface. Using transmission and scanning electron microscopy, morphological and structural characteristics of the electrodeposits have been investigated. Spongy deposits are made of whiskers or microdendrites which grow from a compact substrate. Dendrites obtained at high current density are two-dimensional or three-dimensional. They are initiated by a nucleation process.

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锌电解沉积形态的电子显微镜研究
在碱性或酸性介质中制备的锌镀层具有海绵状、致密状和枝状三个连续的增流特性。这一序列与最近的一些电化学动力学研究很好地吻合,这些研究预测了在特殊条件下表面上的电流分布。利用透射电镜和扫描电镜研究了镀层的形态和结构特征。海绵状沉积物是由晶须或微枝晶组成的,它们生长在致密的基质上。在高电流密度下得到的枝晶是二维或三维的。它们是由成核过程引起的。
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Subject index Author index Influence of hexamine on the formation of zinc phosphate coatings on steel Cobalt-chromium coatings by electrodeposition: Review and initial experimental studies Phase transformations in electrolytic silver-zinc alloys
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