Physical and Mechanical Properties of Palm Kernel Oil-Based Polyester Polyurethane/Multi-Walled Carbon Nanotube Composites

K. M. Amin, M. A. Zailani, N. Zulkifli, K. Badri
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引用次数: 1

Abstract

In this study, polyurethane (PU) films from palm ke rn l oil-based polyester (PKO-p) incorporated multi -walled carbon nanotubes (MWNTs) are prepared via a evaporative casting method. Nanoparticle fluid d ispersions containing 0.02%, 0.03%, and 0.05% wt. of MWNTs are added into PKO-p based resin and mixed by digital probe sonicator fo r 30 min followed by mixing with isocyanate to produce PU-MW NTs composite films. The mechanical properties, swe lling, water vapour transmission rate (WVTR) and conductiv ity of the PU-MWNTs composite films are examined. R esults show that the toughness (T) or flexibility, the ten sile strength (TS), and Young’s modulus (YM) values of PU-MWNTs composite films increase with the increasing concen trations of MWNT. In contrast, the water vapour tra nsmission rate (WVTR) and swelling test of PU-MWNTs composite film s decrease with the increase of MWNT concentrations . For conductivity testing, the film with 0.05 wt.% MWNT (PU-5) has the highest conductivity value at 2.19 x 10 S cm. In summary, incorporation of MWNTs has improved the me chanical properties of the polyurethane composites film .
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棕榈仁油基聚酯聚氨酯/多壁碳纳米管复合材料的物理力学性能
本研究采用蒸发铸造法制备了棕榈油基聚酯(PKO-p)复合多壁碳纳米管(MWNTs)聚氨酯(PU)薄膜。将含有0.02%、0.03%和0.05%重量纳米纳米管的纳米颗粒流体分散体加入PKO-p基树脂中,用数字探针超声器混合30 min,然后与异氰酸酯混合,制得PU-MW纳米管复合膜。测试了PU-MWNTs复合膜的力学性能、热应力、水蒸气透过率和电导率。结果表明,pu -MWNT复合膜的韧性(T)或柔韧性、弹性强度(TS)和杨氏模量(YM)值随MWNT浓度的增加而增加。PU-MWNTs复合膜的水蒸气透过率(WVTR)和溶胀试验均随MWNT浓度的增加而降低。对于电导率测试,0.05 wt.% MWNT (PU-5)的薄膜电导率最高,为2.19 x 10 S cm。综上所述,纳米碳管的加入改善了聚氨酯复合薄膜的力学性能。
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