T. Takekoshi, J. E. Kochanowski, J. S. Manello, M. J. Webber
{"title":"Polyetherimides. II. High-temperature solution polymerization","authors":"T. Takekoshi, J. E. Kochanowski, J. S. Manello, M. J. Webber","doi":"10.1002/polc.5070740111","DOIUrl":null,"url":null,"abstract":"<p>The polymerization and characterization of the ether-containing aromatic polyimides of the following general structure are presented.</p><p><span>\n <picture>\n <source></source></picture>\n </span></p><p>The polymerization was conducted in one step in homogeneous solution of m-cresol at high temperatures. Typical polyeterimides (PEI) were noncrystalline and showed excellent thermal stability. Among 46 polymers synthesized, only two were crystalline. PEI had glass transition temperatures from 178° to 277°C and exhibited excellent processibility. Many PEI were also soluble in dipolar aprotic solvents and chlorinated hydrocarbons.</p>","PeriodicalId":16867,"journal":{"name":"Journal of Polymer Science: Polymer Symposia","volume":"74 1","pages":"93-108"},"PeriodicalIF":0.0000,"publicationDate":"1986-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1002/polc.5070740111","citationCount":"58","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Polymer Science: Polymer Symposia","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/polc.5070740111","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 58
Abstract
The polymerization and characterization of the ether-containing aromatic polyimides of the following general structure are presented.
The polymerization was conducted in one step in homogeneous solution of m-cresol at high temperatures. Typical polyeterimides (PEI) were noncrystalline and showed excellent thermal stability. Among 46 polymers synthesized, only two were crystalline. PEI had glass transition temperatures from 178° to 277°C and exhibited excellent processibility. Many PEI were also soluble in dipolar aprotic solvents and chlorinated hydrocarbons.