Polyetherimides. II. High-temperature solution polymerization

T. Takekoshi, J. E. Kochanowski, J. S. Manello, M. J. Webber
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引用次数: 58

Abstract

The polymerization and characterization of the ether-containing aromatic polyimides of the following general structure are presented.

The polymerization was conducted in one step in homogeneous solution of m-cresol at high temperatures. Typical polyeterimides (PEI) were noncrystalline and showed excellent thermal stability. Among 46 polymers synthesized, only two were crystalline. PEI had glass transition temperatures from 178° to 277°C and exhibited excellent processibility. Many PEI were also soluble in dipolar aprotic solvents and chlorinated hydrocarbons.

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Polyetherimides。2高温溶液聚合
介绍了以下一般结构的含醚芳族聚酰亚胺的聚合和表征。该聚合反应在间甲酚均相高温下一步完成。典型的聚醚酰亚胺(PEI)是非晶态的,具有良好的热稳定性。在合成的46种聚合物中,只有两种是结晶性的。PEI的玻璃化转变温度为178 ~ 277℃,具有良好的可加工性。许多PEI还可溶于偶极非质子溶剂和氯化烃。
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