Application of an innovative draw solute in forward osmosis (FO) processes

N. Nguyen, H. Nguyen, Shiao‐Shing Chen, X. Bui
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Abstract

: More attention is being paid to forward osmosis (FO) as a breakthrough technology to tackle environmental pollution due to advantages such as high contaminant removal and low energy consumption. Nevertheless, FO applications remain limited by the lack of ideal draw solutes that simultaneously achieve high permeate flux and low salt leakage flux. Therefore, this paper aims to increase water flux while maintaining low reverse salt diffusion by using a low concentration of a highly charged organic EDTA compound coupled with inorganic NaCl salt as a novel draw solute. Results of the FO performance revealed that a draw solute of 0.3 M EDTA-2Na mixed with 0.6 M NaCl yielded a higher water flux (J w =8.82 l/m 2 h) when compared to 0.9 M NaCl only (J w =7.61 l/m 2 h). Moreover, the FO-membrane distillation system produced good quality drinking water with a total dissolved solid (TDS) of <5 mg/l from the permeate stream originating from influent brackish water with a TDS of 6000 mg/l. The analysis results from scanning electron microscopy and energy dispersive X-ray spectroscopy (SEM-EDX) images observed a cake layer of NaCl on the FO membrane surface.
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一种创新的吸收溶质在正向渗透(FO)过程中的应用
正渗透技术(FO)由于具有高去除率和低能耗等优点,作为一项解决环境污染的突破性技术,越来越受到人们的关注。然而,由于缺乏同时实现高渗透通量和低盐泄漏通量的理想拉伸溶质,FO的应用仍然受到限制。因此,本文旨在通过使用低浓度的高电荷有机EDTA化合物偶联无机NaCl盐作为新型引出溶质,在增加水通量的同时保持低逆向盐扩散。结果表明,与仅添加0.9 M NaCl (jw =7.61 l/ M 2 h)相比,添加0.3 M EDTA-2Na和0.6 M NaCl可获得更高的水通量(J w =8.82 l/ M 2 h)。此外,FO-膜蒸馏系统可生产出总溶解固体(TDS) <5 mg/l的优质饮用水,其总溶解固体(TDS)为6000 mg/l。扫描电镜和能量色散x射线能谱(SEM-EDX)分析结果显示,在FO膜表面有一层饼状的NaCl。
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