Non Linear Dielectric Phenomenon in BaTiO3 - Bi (Ti1-xMgx)O3 . Ceramic Material

D. Suastiyanti, P. Rupajati, M. Wijaya
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Abstract

The distinguishing characteristic of an insulator is its resistivity. An insulator has a higher resistivity than a semiconductor or conductor and has high dielectric properties. The adjustable dielectric property is characterized by a change in the permittivity of the dielectric under an applied electric field, this phenomenon is called "dielectric nonlinearity" (dielectric tunability properties). With these properties, a new phenomenon will arise adjustable dielectric properties in dielectric ceramic materials. The aim of this research is to observe the non-linear dielectric phenomenon in BaTiO3-Bi(Ti1-xMgx)O3 ceramic material with x= 0.5, 0.6, 0.7, 0.8 and 0.9. Ceramic materials were synthesized using the sol-gel method which produced nano-sized powders. Impedance data was measured using an impedance analyzer (Solartron SI 1260, Solartron Metrology, West Sussex, UK) in a frequency range of 100 Hz to 500 Hz with an ac measuring voltage of 0.1 V. Dielectric tunability properties were measured from 0oC to 250oC using an automatic component analyzer. at 10 kHz. All samples show the phenomenon of dielectric tunability with different maximum permittivity. The highest permittivity was obtained at x= 0.6 but the highest transition temperature where non-linear phenomena occurred was found in the sample with x= 0.5.
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BaTiO3 - Bi (Ti1-xMgx)O3的非线性介电现象。陶瓷材料
绝缘体的显著特性是它的电阻率。绝缘体具有比半导体或导体更高的电阻率,并具有高介电性能。介电特性的可调性表现为在外加电场作用下介电常数的变化,这种现象称为“介电非线性”(介电可调性)。利用这些特性,将会出现介电陶瓷材料介电性能可调的新现象。本研究的目的是观察x= 0.5, 0.6, 0.7, 0.8和0.9时BaTiO3-Bi(Ti1-xMgx)O3陶瓷材料中的非线性介电现象。采用溶胶-凝胶法制备陶瓷材料,制备纳米粉体。阻抗数据的测量使用阻抗分析仪(Solartron SI 1260, Solartron Metrology, West Sussex, UK),频率范围为100 Hz至500 Hz,交流测量电压为0.1 V。使用自动成分分析仪在0 ~ 250℃范围内测量介电可调性。10千赫。所有样品均表现出不同最大介电常数的介电可调谐现象。介电常数在x= 0.6时最高,而非线性现象发生的最高转变温度出现在x= 0.5时。
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