R.J.H. Clark, D.L. Kepert, R.S. Nyholm, G.A. Rodley
{"title":"Low-frequency infra-red studies (200–500 cm−1) on complexes containing the (Mo6Cl8)4+ and (W6Cl8)4+ cores","authors":"R.J.H. Clark, D.L. Kepert, R.S. Nyholm, G.A. Rodley","doi":"10.1016/0371-1951(66)80214-X","DOIUrl":null,"url":null,"abstract":"<div><p>The infra-red active metal-chlorine vibrational modes of compounds containing the (Mo<sub>6</sub>Cl<sub>8</sub>)<sup>4+</sup> and (W<sub>6</sub>Cl<sub>8</sub>)<sup>4+</sup> cores have been studied above 200 cm<sup>−1</sup>. Two bands associated with vibrations of the cage are observed in all cases, and the correlation between their energies and the presence of other ligands is discussed.</p></div>","PeriodicalId":101180,"journal":{"name":"Spectrochimica Acta","volume":"22 10","pages":"Pages 1697-1700"},"PeriodicalIF":0.0000,"publicationDate":"1966-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0371-1951(66)80214-X","citationCount":"19","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica Acta","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/037119516680214X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 19
Abstract
The infra-red active metal-chlorine vibrational modes of compounds containing the (Mo6Cl8)4+ and (W6Cl8)4+ cores have been studied above 200 cm−1. Two bands associated with vibrations of the cage are observed in all cases, and the correlation between their energies and the presence of other ligands is discussed.
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