Step-Up Concentration Method for Chemical Agents’ Adsorption Measurement in Porous Media

V. Lompik, N. Dadakin, M. Nukhaev, K. Rymarenko, Artem Makatrov, Ildus Zaynullin, D. Bikmeev
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Abstract

Before implementing any chemical enhanced oil recovery project at the field, it is very important to carry out a feasibility study, which is impossible without determining their effectiveness under laboratory conditions. The task of laboratory research is to determine all the parameters of surfactant and polymer solutions, necessary for further analytical evaluation and reservoir simulation. It is necessary to conduct laboratory experiments to perform technical and economic assessment of the chemical EORs implementation. One of the most important issues here is to determine the amount of reagent held in the pore space of the reservoir. The retention parameter determines how much reagent needs to be injected to achieve the required displacement efficiency. It directly affects reagent consumption and economic efficiency. This paper discusses various methods for determining the amount of reagent retained in the reservoir; it can be surfactant species or a polymer. To solve the problem of reducing the time for the experimental part, an algorithm of an experiment was developed, which makes it possible to determine the retention parameters in a shorter time and with less labor. This method was tested and showed its effectiveness in the course of a technical and economic study on the possibility of implementing polymer flooding for a field in Eastern Siberia. As a result of the experiments, the relationships between the surfactant or polymer retention and their concentration, and also between permeability and the amount of reagent adsorbed were found. The effect of salinity on the retention parameter was determined, the fact of desorption for both surfactants and polymers was revealed. Inaccessible pore volume for polymer was determined.
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化学试剂在多孔介质中的吸附量测定的强化浓度法
在油田实施任何化学提高采收率项目之前,进行可行性研究是非常重要的,如果没有在实验室条件下确定其有效性,就不可能进行可行性研究。实验室研究的任务是确定表面活性剂和聚合物溶液的所有参数,为进一步的分析评价和油藏模拟所必需。对化学EORs的实施进行技术经济评价,有必要进行实验室实验。这里最重要的问题之一是确定储层孔隙空间中所含试剂的量。保留参数决定了需要注入多少试剂才能达到所需的置换效率。它直接影响试剂的消耗和经济效益。本文讨论了测定储层中试剂残留量的各种方法;它可以是表面活性剂,也可以是聚合物。针对减少实验部分时间的问题,开发了一种实验算法,可以在更短的时间内以更少的人工确定保留参数。在对东西伯利亚某油田实施聚合物驱的可能性进行技术和经济研究的过程中,对该方法进行了测试,并证明了其有效性。实验结果表明,表面活性剂或聚合物的保留率与它们的浓度有关,渗透率与吸附试剂的量有关。确定了矿化度对保留参数的影响,揭示了表面活性剂和聚合物的脱附现象。测定了聚合物的不可达孔体积。
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