Synthesis of Amino Acid-derived Curing Reagents Containing a Disulfide Bond and Their Application to Anionic UV Curing Materials

Pub Date : 2021-06-11 DOI:10.2494/photopolymer.34.529
M. Furutani, Kako Maeno, Arata Tanaka
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Abstract

4. Conclusion We have designed and synthesized of a novel molecule, BFBZA, and found that the hybrid amorphous film of BFBZA with BA exhibited reversible change in emission color in response to exhaled breath whereas BFBZA–PFBA film did not change the emission color. In our previous paper [21,23], acidity levels of organic acids were the important factor for providing hybrid films that exhibit reversible changes in object colors and emission colors in response to moisture. The present study suggested that the basicity level of emitting material was also the important factors, that is, the balance of acidity level of organic acid and basicity level of emitting amorphous molecular materials plays a role for exhibiting reversible change in emission color. Further studies are in progress.
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含二硫键氨基酸衍生固化剂的合成及其在阴离子UV固化材料中的应用
4. 结论我们设计并合成了一种新型分子BFBZA,发现BFBZA与BA的杂化非晶膜在呼气时发射色发生可逆变化,而BFBZA - pfba膜不改变发射色。在我们之前的论文[21,23]中,有机酸的酸度水平是提供杂化膜的重要因素,这些杂化膜在响应水分时表现出物体颜色和发射颜色的可逆变化。本研究表明,发光材料的碱度水平也是重要的影响因素,即有机酸的酸度水平与发光非晶态分子材料的碱度水平的平衡对发光颜色呈现可逆变化起着重要的作用。进一步的研究正在进行中。
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