Effect of pulse stress on surface charge of epoxy nanocomposites with TiO2 particles

B. Du, J. Zhang, Jie Li, L. Wang, Kai Wu
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引用次数: 3

Abstract

Epoxy resin has become an integral part of electronic and electrical devices where the material is exposed to pulse stress. Surface charge accumulation and decay of charged dielectric materials are very important parameters related to the electrical properties of the material. Nano-composite technology makes it possible to improve electrical properties of insulating materials. Therefore, it is important to investigate the dynamic behavior of surface charge decay influenced by the nano filler on epoxy resin. In this paper, it was attempted to clarify the effect of pulse stress on the electrical properties of epoxy resin nanocomposites focused on the surface charge accumulation and decay based on the TiO2 nano-filler. Prior to test, the samples were prepared by dispersing nano-scale TiO2 into epoxy resin by mixing with shear force. Corona charging and decay tests were independently performed at room temperature with the same humidity. The surface charge distribution was measured by means of an electrostatic voltmeter. Obtained results show the dependence of the accumulated charge density as well as the charge decay rate upon the different nano filler loading that is varied as a function of the rise time of pulse stress. It is suggested that the charge dynamics is dependent upon the characteristics of localized surface states that are altered by the nano filler induced chemical reactions.
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脉冲应力对TiO2纳米环氧复合材料表面电荷的影响
环氧树脂已成为电子和电气设备的组成部分,其中材料暴露在脉冲应力下。带电介质材料的表面电荷积累和衰减是关系到材料电学性能的重要参数。纳米复合技术为提高绝缘材料的电性能提供了可能。因此,研究纳米填料对环氧树脂表面电荷衰减的动态影响具有重要意义。本文试图阐明脉冲应力对环氧树脂纳米复合材料电学性能的影响,重点研究了基于TiO2纳米填料的环氧树脂纳米复合材料的表面电荷积累和衰变。在测试之前,通过剪切力将纳米级TiO2分散到环氧树脂中制备样品。电晕充电和衰减试验分别在室温、相同湿度条件下进行。用静电伏特计测量了表面电荷分布。结果表明,不同纳米填料的负载对累积电荷密度和电荷衰减率的影响随脉冲应力上升时间的变化而变化。结果表明,电荷动力学取决于纳米填料引起的化学反应所改变的局部表面态的特征。
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