Probing intermolecular interactions in a binary mixture of deep eutectic solvents with DMSO by impulsive stimulated Raman spectroscopy

G. Bhutani, Anita Yadav, A. De, V. Yadav
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Abstract

The physicochemical properties of deep eutectic solvents (DESs) can be altered in binary mixture with co-solvents like water, dimethyl sulfoxide (DMSO), etc. due to the synergistic effect of hydrogen bond donors-acceptors (HBDs-HBAs) that arises from the interactions of DESs with (organic) solvents. We investigated the intermolecular interactions of DES (1,3-Propanediol-based) of varying compositions in binary mixture with DMSO and observed the emergence of a new vibrational mode using impulsive stimulated Raman spectroscopy (ISRS). © Anita Publications. All rights reserved.
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用脉冲受激拉曼光谱探测深共晶溶剂与DMSO二元混合物中的分子间相互作用
深层共晶溶剂(DESs)在与水、二甲基亚砜(DMSO)等共溶剂的二元混合物中,由于DESs与(有机)溶剂相互作用产生氢键供体-受体(HBDs-HBAs)的协同作用,其物理化学性质会发生改变。我们研究了不同成分的DES(1,3-丙二醇基)在二元混合物中与DMSO的分子间相互作用,并利用脉冲受激拉曼光谱(ISRS)观察到一种新的振动模式的出现。©Anita Publications。版权所有。
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