{"title":"The secondary ion mass spectrum of glycerol-d5: Evidence for radical cation intermediates","authors":"Woodfin V. Ligon Jr","doi":"10.1016/0020-7381(83)85040-2","DOIUrl":null,"url":null,"abstract":"<div><p>Particle bombardment of liquid glycerol deuterated on carbon has provided evidence for (MD)<sup>+</sup> ion formation via a radical cation intermediate. This discovery has important mechanistic implications for the ionization of compounds dissolved in glycerol.</p></div>","PeriodicalId":13998,"journal":{"name":"International Journal of Mass Spectrometry and Ion Physics","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1983-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-7381(83)85040-2","citationCount":"31","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Mass Spectrometry and Ion Physics","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020738183850402","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 31
Abstract
Particle bombardment of liquid glycerol deuterated on carbon has provided evidence for (MD)+ ion formation via a radical cation intermediate. This discovery has important mechanistic implications for the ionization of compounds dissolved in glycerol.