Determination of optimal conditions for hydrogenolysis of sulfur compounds of straight-run jet fuel

D. Borisanov, M. A. Bubnov, N. N. Vakhromov, I. V. Gudkevich, E. Dutlov, N. Karpov, A. Gritsenko, A. Maximov, L. Rathkeen
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Abstract

This paper describes comparison of characteristics of jet fuels TS-1 and RT, their production technologies and peculiarities. In case when total sulfur content minus mercaptans content in straight-run jet fuel is less than 0,2 % by weight it is advisable to use hydrotreating, in other cases hydrotreating might be treated as excessible and it is efficient to remove only mercaptans. The design, principle of operation and an example of application of laboratory unit for determination of optimal parameters for hydrogenolysis of sulfur compounds of typical straight-run jet fuel is described. The possibility to obtain fuel grade TS-1 with the use of hydrodemercaptanization is shown.
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直馏喷气燃料硫化物氢解最佳条件的测定
本文比较了TS-1和RT两种喷气燃料的特性、生产工艺和特点。当直馏喷气燃料中总硫含量减去硫醇含量的重量比小于0.2%时,建议使用加氢处理,在其他情况下,加氢处理可能被认为是多余的,只去除硫醇是有效的。介绍了一种用于确定典型直馏喷气燃料硫化物氢解最佳参数的实验室装置的设计、工作原理和应用实例。展示了利用加氢脱氢法获得燃料级TS-1的可能性。
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