NMR relaxation in adsorbed water

K Overloop, L van Gerven
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引用次数: 19

Abstract

The NMR relaxation behavior of the proton magnetization in adsorbed water is investigated. Longitudinal as well as transverse relaxation of the adsorbed water as a whole shows a distinct nonexponentiality and the nature of this nonexponentiality is studied. Different methods of fitting distribution of relaxation times are examined and various simulated and experimental decay curves are submitted to these fitting methods. The results of these fittings clearly indicate that both the longitudinal and the transverse relaxation of the proton magnetization in adsorbed water is related to two or three discrete components and that there is certainly no broad distribution of relaxation times present in these water-adsorbent systems.

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吸附水的核磁共振弛豫
研究了质子磁化在吸附水中的核磁共振弛豫行为。吸附水的纵向和横向弛豫作为一个整体表现出明显的非指数性,并研究了这种非指数性的性质。研究了不同的松弛时间分布拟合方法,并给出了不同的模拟和实验衰减曲线。这些结果清楚地表明,质子磁化在吸附水中的纵向和横向弛豫与两个或三个离散分量有关,并且在这些水吸附系统中肯定不存在广泛的弛豫时间分布。
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