GADOLINIUM SORPTION ON MULTI-WALLED CARBON NANOTUBES

D. Maksin, M. Vukčević, Tatjana Đurkić, Ivana Stanišić, T. Bakić, Milena Radomirović, A. Onjia
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引用次数: 1

Abstract

Rare earth metals are deemed to be the materials of future due to their numerous applications including medical diagnostics, nuclear facilities, petroleum industry, etc. In this paper, multi-walled carbon nanotubes, which possess unique physicochemical properties, were evaluated as sorbents for lanthanoid gadolinium from aqueous solutions. The pH-dependent sorption behavior of Gd was studied in the pH range from 3 to 11 at room temperature (298 K). Equilibrium data over a range of initial Gd concentrations of 5−50 mg L−1 was analyzed with Langmuir, Freundlich and Redlich-Peterson models. Sorption kinetics was fitted with the pseudo-first-order, the pseudo-second-order and fractional power kinetic models.
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多壁碳纳米管对钆的吸附
稀土金属在医疗诊断、核设施、石油工业等领域有着广泛的应用,被认为是未来的材料。本文研究了具有独特物理化学性质的多壁碳纳米管作为水溶液中类镧钆的吸附剂。在室温(298 K)下,研究了Gd在pH 3 ~ 11范围内的pH依赖性吸附行为。使用Langmuir、Freundlich和Redlich-Peterson模型分析了初始Gd浓度为5 ~ 50 mg L−1范围内的平衡数据。吸附动力学符合拟一阶、拟二阶和分数阶动力学模型。
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