{"title":"Electrocoagulation of Azo-2-Naphthol Dye Using Aluminium Electrodes: Effect of Solvent and Kinetics of Adsorption","authors":"V. Mkpenie, O. Abakedi","doi":"10.3923/CRC.2015.34.43","DOIUrl":null,"url":null,"abstract":"1-Phenylazo-2-naphthol (PAN) was subjected to electrocoagulation using a 0.3 A d.c electrolytic cell in various solvents including ethanol, acetone, benzene and n-hexane. The extent of decolourization of PAN in the solvents has been determined. The highest decolourization was achieved in ethanol with colour removal efficiency of 63% within the first 15 min and 79% after 120 min of electrocoagulation. The decolourization of PAN in the solvents is observed to follow the order: Ethanol>n-hexane>benzene>acetone. The electrocoagulation data has also been interpreted based on adsorption kinetic models. Electrocoagulation of PAN in all the solvents obeyed the pseudo-second order kinetic model and Elovich kinetic model.","PeriodicalId":10941,"journal":{"name":"Current Research in Chemistry","volume":"30 1","pages":"34-43"},"PeriodicalIF":0.0000,"publicationDate":"2015-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Current Research in Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3923/CRC.2015.34.43","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 5
Abstract
1-Phenylazo-2-naphthol (PAN) was subjected to electrocoagulation using a 0.3 A d.c electrolytic cell in various solvents including ethanol, acetone, benzene and n-hexane. The extent of decolourization of PAN in the solvents has been determined. The highest decolourization was achieved in ethanol with colour removal efficiency of 63% within the first 15 min and 79% after 120 min of electrocoagulation. The decolourization of PAN in the solvents is observed to follow the order: Ethanol>n-hexane>benzene>acetone. The electrocoagulation data has also been interpreted based on adsorption kinetic models. Electrocoagulation of PAN in all the solvents obeyed the pseudo-second order kinetic model and Elovich kinetic model.