Oxidatively induced carbon chain growth at a ditungsten centre

I. Bartlett, N. Connelly, Legge, Antonio Martín, Bernhard Metz, A. Orpen
{"title":"Oxidatively induced carbon chain growth at a ditungsten centre","authors":"I. Bartlett, N. Connelly, Legge, Antonio Martín, Bernhard Metz, A. Orpen","doi":"10.1039/CC9960001877","DOIUrl":null,"url":null,"abstract":"X-Ray structural and EHMO studies show that two electrons are sequentially removed from a W–W δ* orbital on oxidation of the bis(metallacyclopentadiene) complex [W2(µ-C4Me4)2(η-C5H5)2] to [W2(µ-C4Me4)2(η-C5H5)2]z+(z= 1,2); the dication undergoes C–C coupling and proton loss in boiling MeCN to give [W2(µ-C8Me7CH2)(η-C5H5)2]+ which adds hydride ion to form the metallacyclononatetraene complex [W2(µ-C8Me8)(η-C5H5)2].","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"32 1","pages":"1877-1878"},"PeriodicalIF":0.0000,"publicationDate":"1996-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/CC9960001877","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2

Abstract

X-Ray structural and EHMO studies show that two electrons are sequentially removed from a W–W δ* orbital on oxidation of the bis(metallacyclopentadiene) complex [W2(µ-C4Me4)2(η-C5H5)2] to [W2(µ-C4Me4)2(η-C5H5)2]z+(z= 1,2); the dication undergoes C–C coupling and proton loss in boiling MeCN to give [W2(µ-C8Me7CH2)(η-C5H5)2]+ which adds hydride ion to form the metallacyclononatetraene complex [W2(µ-C8Me8)(η-C5H5)2].
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
氧化诱导碳链生长在钨中心
x射线结构和EHMO研究表明,双金属环戊二烯配合物[W2(µ-C4Me4)2(η-C5H5)2]氧化为[W2(µ-C4Me4)2(η-C5H5)2]z+(z= 1,2)时,两个电子从W-W δ*轨道上依次移出;该反应在沸腾的MeCN中发生C-C偶联和质子损失,生成[W2(µ-C8Me7CH2)(η-C5H5)2]+,并与氢化物离子形成金属环壬四烯配合物[W2(µ-C8Me8)(η-C5H5)2]。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
自引率
0.00%
发文量
0
审稿时长
2 months
期刊最新文献
Competing pathways in the phototransposition of pyrazoles Total synthesis of (+)-polyoxin J Symmetric bis-benzimidazoles, a new class of sequence-selective DNA-binding molecules Aldehydes and Ketones as Dipolarophiles. Application to the Synthesis of Oxapenams Chemoselective platinum(0)-catalysed hydrophosphination of ethyl acrylate
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1