Features of the I-IV groups of aromatic hydrocarbons of theWest-Aрsheronoil

M. A. Najafova, Yu.A. Abdullayeva, A.M. Mаmmedov, S. Aliyeva, N. G. Alekperova, N.A. Rzayeva, R. J. Kasumov
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Abstract

The composition and paramagnetism of groups I-IV of aromatic hydrocarbons of the West-Арsheron oil were studied by UV and EPR spectroscopy. It was found that in all I-III groups of heavy oil there are derivatives of benzene, naphthalene, phenanthrene and anthracene, the quantitative content of which increases as the are fractionated. It is show that there are no paramagnetic particles in the EPR spectrum o group I AU of the West-Aрsheron oil. In group II of the AU, the EPR spectrum of the substituted hydrocarbon radical with Нwidh=7,5mt, g = 2,07 Mn+2 is recorded in a small amount, and in a small amount it is closely related to asphaltene radicals with Hwidh=1.1mt, g=2.0028 and a small amount on Mn+2idue. A small amount of Co, shielded by asphaltene radicals, is recorded on the spectrum.
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西部蒿油I-IV族芳烃特征
用紫外光谱和电子磁共振光谱研究了西部-Арsheron油中芳烃I-IV族的组成和顺磁性。结果表明,重油ⅰ~ⅲ基团中均存在苯、萘、菲、蒽的衍生物,其定量含量随着分馏的增加而增加。结果表明,西埃尔松油ⅰ族AU的EPR谱中不存在顺磁颗粒。在AU的II族中,含有Нwidh= 7.5 mt, g= 2,07 Mn+2的取代烃自由基的EPR谱少量记录,少量与h宽度=1.1mt, g=2.0028的沥青质自由基密切相关,少量在Mn+2上。被沥青质自由基屏蔽的少量Co在光谱上被记录下来。
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