Deodorization of model biogas by meansof novel non-ionic deep eutectic solvent

IF 1.4 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Archives of Environmental Protection Pub Date : 2023-04-01 DOI:10.24425/AEP.2020.132524
E. Słupek, E. Słupek, P. Makoś, P. Makoś, Patrycja Makoś-Chełstowska, J. Gębicki, J. Gebicki
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引用次数: 12

Abstract

The paper presents new non-ionic deep eutectic solvent (DES) composed of natural and non-toxic components i.e. guaiacol, camphor and levulinic acid in 1:1:3 molar ratio as a promising absorbent for removal of selected volatile organic compounds (VOCs) including dichloromethane, toluene, hexamethyldisiloxane and propionaldehyde from model biogas. The affi nity of DES for VOCs was determined as vapour-liquid coeffi cients and the results were compared with several well-known DESs based on quaternary ammonium salt as well as n-hexadecane and water. For new DES, the absorption process was carried out under dynamic conditions. The results indicate that non-ionic DES has high affi nity and capacity for VOCs being comparable to n-hexadecane. In addition, absorbed VOCs could be easily desorbed from DES using activated carbon and absorbent could be re-use minimum five times without signifi cant loss of absorption capacity
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新型非离子型深共熔溶剂对模型沼气的脱臭研究
本文介绍了一种由愈创木酚、樟脑和乙酰丙酸按1:1:3的摩尔比组成的新型非离子深度共晶溶剂,它是一种很有前途的吸收剂,可用于去除模型沼气中的挥发性有机化合物(VOCs),包括二氯甲烷、甲苯、六甲基二硅氧烷和丙醛。用气液系数测定了DES对挥发性有机化合物的亲和力,并与几种知名的季铵盐、正十六烷和水的DES进行了比较。对于新des,吸收过程在动态条件下进行。结果表明,非离子型DES对与十六烷相当的VOCs具有较高的亲和力和吸附能力。此外,吸附的挥发性有机化合物可以很容易地用活性炭从DES中解吸,并且吸收剂可以重复使用至少5次而不会明显损失吸收能力
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来源期刊
Archives of Environmental Protection
Archives of Environmental Protection ENVIRONMENTAL SCIENCES-
CiteScore
2.70
自引率
26.70%
发文量
0
期刊介绍: Archives of Environmental Protection is the oldest Polish scientific journal of international scope that publishes articles on engineering and environmental protection. The quarterly has been published by the Institute of Environmental Engineering, Polish Academy of Sciences since 1975. The journal has served as a forum for the exchange of views and ideas among scientists. It has become part of scientific life in Poland and abroad. The quarterly publishes the results of research and scientific inquiries by best specialists hereby becoming an important pillar of science. The journal facilitates better understanding of environmental risks to humans and ecosystems and it also shows the methods for their analysis as well as trends in the search of effective solutions to minimize these risks.
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