Detection of Odor Compounds in Deep-sea Sediment Cores from Sagami Bay and Izu-Bonin Trench using Gas Chromatography-olfactometry (GC-O)

Misato Matsumoto, H. Nomaki, S. Kawagucci, Y. Koga, Taiki Higuchi, Hideaki Matsumoto, Kou Nishimuta, N. Ryuda, D. Ueno
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Abstract

The usage of synthetic fragrances which contained in pharmaceuticals and personal care products (PPCPs) have been increasing in Japan, and environmental discharge of those chemicals have also been increasing. This study tried to detect odor compounds in sediment core samples collected from 1 , 400 and 9 , 200 m water depths, in Sagami Bay and Izu-Bonin Trench, Japan. Odor activities in sediment core samples were detected by Gas Chromatography-Olfactometry (GC-O) which detects odor chemicals using human olfaction. It is the first report which analyzed the odor activities in deep-sea sediments. By comparing odor activities found in deeper and surface core samples, six odor compounds were tentatively defined as anthropogenic source. It is required to conduct the novel research topic of “ environmental risk assessment for odor compounds ” . The GC-O could be useful technique to find the emerging chemicals on the research fields of environmental chemistry.
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相模湾和伊豆-波宁海沟深海沉积物岩心中气味成分的气相色谱-气味测定
在日本,药品和个人护理产品(PPCPs)中含有的合成香料的使用量一直在增加,这些化学品的环境排放也在增加。这项研究试图在日本相模湾和伊豆-波宁海沟的1400米和9200米水深的沉积物岩心样本中检测气味化合物。采用气相色谱-嗅觉法(GC-O)检测沉积物岩心样品中的气味活性,该方法利用人的嗅觉检测气味化学物质。这是对深海沉积物中气味活动进行分析的首次报道。通过比较深层和表层岩心样品中发现的气味活性,初步确定了六种气味化合物为人为来源。需要开展“气味化合物环境风险评价”这一新颖的研究课题。在环境化学研究领域,气相色谱- o是一种有用的发现新兴化学物质的技术。
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